TeardownSeptember 12, 20262 min read

Aduro's Hydrochemolytic Route: Water-Mediated Plastic Conversion, and the Refinery Problem It Does Not Escape

Aduro says its water-based chemistry converts waste plastic and heavy oil at lower temperatures than pyrolysis. Even if that holds, the output is still a feedstock that a refinery has to finish.

Aduro's Hydrochemolytic Route: Water-Mediated Plastic Conversion, and the Refinery Problem It Does Not Escape
01

Aduro Clean Technologies promotes Hydrochemolytic Technology (HCT): waste plastics and heavy hydrocarbons converted in water with a catalyst at moderate temperature and pressure, producing lower-boiling liquid hydrocarbons.

A refinery. Every plastic-to-liquid process ends here, and that dependency is usually understated.
A refinery. Every plastic-to-liquid process ends here, and that dependency is usually understated.Photo: Wikimedia Commons, CC BY-SA 4.0
02

The chemistry claim

250-350C
claimed HCT operating range, versus 450-550C for pyrolysis

Conventional pyrolysis heats plastic to 450-550C in the absence of oxygen and cracks it thermally. The reaction is uncontrolled, yields a broad product slate, and produces coke that fouls reactors.

HCT uses water near or above its critical region as both reaction medium and hydrogen donor, with a catalyst, at a reported 250-350C. Water at these conditions behaves very differently from ambient water: its dielectric constant drops, it dissolves organics, and it participates directly in bond cleavage. This is real, documented chemistry — hydrothermal liquefaction of biomass works on the same principles.

Where HCT sits relative to pyrolysis, and where its output still has to go.
Where HCT sits relative to pyrolysis, and where its output still has to go.

The plausible advantages: lower temperature, less coke formation, in-situ hydrogen from water rather than added hydrogen gas, and a narrower product distribution.

03

The problem no plastic-to-liquid process avoids

Claimed

Waste plastic converted back into usable hydrocarbon products.

Actually

The output is a mixed hydrocarbon liquid containing chlorine, nitrogen and metal contaminants from the waste stream. It is a refinery feedstock, not a product. Refineries accept it in small blend ratios, at a discount, if at all.

This is the structural constraint on the entire sector. Chlorine from PVC poisons refinery catalysts and corrodes equipment. Nitrogen and oxygen compounds from mixed waste behave badly in downstream units. Refinery operators therefore cap pyrolysis oil at low single-digit percentages of feed, which caps the addressable market regardless of how elegant the conversion chemistry is.

Soft film is the stream everyone points to. It is also the dirtiest, with the most additives and the most residue.
Soft film is the stream everyone points to. It is also the dirtiest, with the most additives and the most residue.Photo: Wikimedia Commons, CC BY-SA 4.0
04

Scale is the other gap

For any hydrothermal process, the question that separates a lab result from a business is continuous solids handling at pressure. Ask how many hours the longest uninterrupted run has been.

A tyre pyrolysis plant. The reactor is the part of the story that is unambiguously physical.
A tyre pyrolysis plant. The reactor is the part of the story that is unambiguously physical.Photo: Zzkysb, CC BY-SA 3.0

Aduro''s published results are at laboratory and small pilot scale. Hydrothermal processes scale badly in one specific way: handling a slurry of solids in high-pressure water continuously, without plugging, erosion or seal failure, is a mechanical problem that has defeated a long line of hydrothermal liquefaction ventures. The chemistry usually survives scale-up. The pumps and let-down valves often do not.

05

What would be persuasive

A thousand-hour continuous run on unsorted post-consumer plastic, a full elemental analysis of the product oil including chlorine, and a named refinery willing to state a blend ratio. Absent those, this is promising chemistry at an early stage, priced by markets as though it were further along.

References and image credits
  1. 01Aduro Clean Technologies
  2. 02US DOE — Hydrothermal liquefaction overview

Photo: Wikimedia Commons, CC BY-SA 4.0 · Photo: Wikimedia Commons, CC BY-SA 4.0 · Photo: Zzkysb, CC BY-SA 3.0